Preparation of 3-aryl-2-aminoindoles, 3-allyl-3-amino-2-iminoindolines, and tetrahydro-[1,4]diazepino[2,3-b]indoles from 3-diazoindolin-2-imines.

نویسندگان

  • Guorong Sheng
  • Kai Huang
  • Shicong Ma
  • Jing Qian
  • Ping Lu
  • Yanguang Wang
چکیده

The rhodium-catalyzed reactions of 3-diazoindolin-2-imines with N,N-dialkylanilines, N-allyl-N-alkylanilines, and N-propargyl-N-alkylanilines and 3-diazoindolin-2-imines furnished 3-aryl-2-aminoindoles, 3-allyl-3-amino-2-iminoindolines, and tetrahydro-[1,4]diazepino[2,3-b]indoles, respectively. 3-Diazoindolin-2-imines acted as precursors of α-imino rhodium carbenes in these transformations.

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عنوان ژورنال:
  • Chemical communications

دوره 51 55  شماره 

صفحات  -

تاریخ انتشار 2015